Вода і водоочисні технології. Науково-технічні вісті, № 2(33)
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Документ Відкритий доступ Production technology and filtering properties of carbon block cartridges(КПІ ім. Ігоря Сікорського; ТОВ «Українська водна спілка», 2022) Braslavska, Y.; Mitchenko, T.; Ponomarov, V.; Maletskyi, Z.; Kosogina, I.In the present paper, the information on the influence of various factors on the carbon block cartridges production technology and their potential impact on the properties of the finished product is presented. The possibilities of increasing the sorption-filtering efficiency of carbon block cartridges are presented. The technical and exploitation characteristics are influenced by the size of the mixture components granules, the physicochemical properties of active carbon and binder polymers, their ratio in the mixture, and the addition of bactericidal additives into the composition. The study of this topic is relevant, as evidenced by the analysis of the increasing number of publications on this matter over the past ten years. However, the production technology of carbon block cartridges is the know-how of manufacturing companies. This information is confirmed by the analysis of the technical characteristics of sixty carbon block cartridges from nine world manufacturers, whose products are WQA certified according to the NSF/ANSI 42 standard. The recommendations given by a number of authors on the size of activated carbon granules in the range from 40 to 120 mesh and polyethylene particles from 80 to 160 mesh with a flow rate of 1.4-3 g/10 min, can be taken as "reference points" in the development of extrusion mixtures with different components ratio. The following factors play an important role in obtaining effective cartridges: the quality of pre-extrusion mixing of the composition, its resistance to delamination during the “transition” from the mixer to the extruder loading zone, extrusion temperature regimes by zones, product cooling temperature, backpressure on the billet leaving the extruder. The information given in this article will be useful when producing new carbon block cartridges, improving the parameters of existing technologies, as well as in the research development of cartridges with new properties.Документ Відкритий доступ Water quality of small rivers in the Pripyat basin: environmental and fishery assessment(КПІ ім. Ігоря Сікорського; ТОВ «Українська водна спілка», 2022) Grokhovska, Y.; Konontsev, S.The study of anthropogenic causes of the deterioration of the state of small rivers is the first step towards their conservation and restoration, improving the human environment as a whole. The aim of the study is the fishery and environmental assessment of water quality of small rivers in the Pripyat River basin (the area of right-bank tributaries in the middle part of the river) within the Rivne region in the northern-west region of Ukraine. The initial data for the assessment have been the results of monitoring (27 physical and chemical indicators) during 2010–2018. The assessment by the integral ecological index (Ie) has shown that the rivers belonged to the II quality class in terms of average values and were characterized as “clean” and “clean enough”. According to the worst values, the rivers belonged to the II-III quality classes and were characterized as “fairly clean” – “slightly polluted” – “moderately polluted”. The best water quality by the Ie index was established for the Zhabichi River within the urban-type settlement of Demydivka. Water quality of the Ustia River below the runoff of the cities of Rivne and Zdolbuniv has corresponded to IV-V classes i.e. was "dirty" and "very dirty" (high content of phosphates, nitrogen compounds, copper, manganese, and zinc). In terms of trophic state, the water of the rivers is mesotrophic (according to average values) and eutrophic (according to the worst values), except for the part of the Ustia River below the runoff of the city of Rivne, where the water is polytrophic. The rivers have failed to meet water quality standards for fishery water use by COD, BOD5, and heavy metals content (Cu, Mn, Fe, Zn).Документ Відкритий доступ The influence of the way of sewage sludge treatment on ammonium nitrogen content in the return wastewater flow(КПІ ім. Ігоря Сікорського; ТОВ «Українська водна спілка», 2022) Sorogovet, V. V.; Markevich, R. M.; Martsul’, V. N.; Sapon, E. G.; Lukashevich, S. O.Wastewater treatment facility receives, in addition to the influent, the return flow after sewage sludge treatment. Thus, the organic load on the facility increases as well as the nitrogen and phosphorus content load. There was studied the effect of different stages of sewage sludge treatment (sludge thickening, mechanical dewatering, storage on the grit bays and in the gathering ponds) on ammonium nitrogen content in the incoming flow. It is established that the most concentrated water by ammonium nitrogen is the return water from the gathering ponds, but the less concentrated is the supernatant water from sludge lagoons. Taking into account volume of the return flow the secondary ammonium nitrogen load from the every stage of sewage sludge treatment is calculated. It is revealed the seasonal and climatic impact on the gathering ponds return flow composition; it is shown that the biggest fluctuations occur in spring-summer period. The dependence of ammonium nitrogen content in the return flow on sludge thickening process time in the sludge lagoons is determined. The load contribution on the treatment facility by ammonium nitrogen in the return flow was 3% in the relation to this in the influent. The conclusion was made that with the existing technology of sewage sludge treatment the isolated scheme of return water treatment is not required. The comparative analysis on the effect of thermophilic and mesophilic conditions of anaerobic sewage sludge treatment on ammonium nitrogen content in the liquor was carried out. It was found that the higher ammonium nitrogen secondary load is created by the liquor of thermophilically treated sewage sludge: it is 16,4% versus 11,8% of mesophilically treated. Hence, the including of anaerobic sewage sludge treatment in the scheme significantly increases the load on treatment facility by ammonium nitrogen. In the conditions of cascade denitrification the distribution of incoming in the denitrification zones water flow is of great importance for providing required content of readily available organic substances. The change of ammonium nitrogen content in this flow will require the adjustment of its volume.Документ Відкритий доступ Preparation of silver-containing natural zeolites with improved porous characteristics as sorbents for water purification(КПІ ім. Ігоря Сікорського; ТОВ «Українська водна спілка», 2022) Patrylak, L.; Nizhnik, B.; Yakovenko, A.; Melnychuk, O.; Pertko, O.The widespread application of Ukrainian natural zeolites in sorption and catalysis is limited by the shortcomings of their porous structure. Chemical modification of zeolites permits significant changes in their properties. The purpose of this work was to obtain silver-containing natural zeolites of the clinoptilolite type with improved porous characteristics by acid treatment and to study their antibacterial properties. Mild dealumination of the rock was carried out using ethylenediaminetetraacetic acid for 15 hours at 90 C, which significantly increased the specific surface area of the clinoptilolite sample to 90 m2 /g, and the volume of micropores to 0.037 cm3 /g, determined by low-temperature nitrogen adsorption/desorption. An establishment of a change in the chemical composition of the sample during processing by X-ray fluorescence analysis was made. Additional modification with silver in the amount of 1 wt % was carried out by impregnation with a solution of silver nitrate. The water of three lakes in Kyiv was studied for the total viable count by means of sowing in nutrient agar. The results were analyzed and a sample of water was selected to evaluate the effectiveness of the synthesized sorbent. The antibacterial properties of zeolite were confirmed with the worst of the water samples, the quality of which, in terms of the total viable count, was improved not only to the norms of surface water but also to the indicators for drinking water.Документ Відкритий доступ Synthesis of TIO2 by solvothermal method and its photocatalytic activity towards Biseptol and Congo red(КПІ ім. Ігоря Сікорського; ТОВ «Українська водна спілка», 2022) Aleksyk, A.; Yanushevska, O.; Dontsova, T.The creation of ceramic membranes with additional functional properties, such as antibacterial and photocatalytic, is a popular and promising area of research in the field of water treatment. The article is devoted to the synthesis of titanium (IV) oxide powders by the solvothermal method for their further usage as a photocatalytic selective layer in ceramic membranes. The study of the peculiarities of the photocatalytic materials synthesis for the creation of photocatalytic and at the same time antimicrobial ceramic membranes on their basis is extremely relevant, because it will allow to develop a method of synthesis of photocatalysts active to various pollutants. Therefore, the aim of the work was the synthesis of TiO2 powders by solvothermal method at different ratios of the starting reagents, the study of their physicochemical properties and the study of their photocatalytic properties in relation to different pollutant – antibiotics and dyes. The obtained powders were characterized by diffraction analysis, infrared spectroscopy, low-temperature nitrogen adsorptiondesorption and scanning electron microscopy. It is established that the ratio of the initial components significantly affects the final properties and characteristics of TiO2 powders. It was shown that the synthesis with a significant excess of the starting reagent (titanium isopropoxide) does not lead to the crystalline TiO2 sample, which was confirmed by diffraction analysis and infrared spectroscopy. The revealed porous structure of all TiO2 samples indicates a high specific surface area in them, which is also consistent with scanning electron microscopy studies. The highest photocatalytic activity is possessed by TiO2 samples, which are nanocomposites of anatase and rutile modifications. Such nanocomposites showed quite high activity towards antibiotics (Biseptol) and anionic dyes (Congo red).Документ Відкритий доступ Investigation of natural flocculants for use in wastewater purification processes(КПІ ім. Ігоря Сікорського; ТОВ «Українська водна спілка», 2022) Solodovnik, T. V.; Yakymenko, I. K.Contaminated industrial wastewater significantly reduces the volume of drinking water. A wide range of composition and insufficient treatment of wastewater from enterprises such as the textile, chemical or metalworking industries, which often fall into water bodies, negatively affect the state of aquatic ecosystems, and that is why it is necessary to carefully select the optimal treatment method. Among the types of wastewater treatment, the coagulation-flocculation process has gained considerable popularity, which occurs due to the adhesive and adsorption properties of coagulants and flocculants, which is widely used in the purification technologies of both natural and industrial wastewater from colloidal particles, radionuclides, phosphates, dyes and suspended particles. Coagulants are able to hydrolyze in water with the formation of various coagulation structures with high adsorption and adhesion properties, flocculants, in turn, contribute to the formation of flakes, sedimentation and filtration, stabilize the cleaning process, improve quality and increase the efficiency of equipment. During the experimental work, the employees of the Department of Chemical Technology and Water Treatment established the advantages of using natural flocculants in the process of wastewater treatment using colored model solutions as an example. A study was made of the influence on the degree of purification of such characteristics as the type of flocculant (for example, chitosan and sodium alginate) and coagulant (Al2(SO4)3-18H2O, ALS, PIX-318), the optimal dose of reagents, the type of dye (direct, active, dispersed) , settling time and content of residual ions. During the research, the Jar-test method was used, the essence of which is to simulate the process of floc formation, which is typical for industrial wastewater treatment plants. The study of the composition of model water samples was carried out using the spectrophotometric analysis method.